doc. RNDr. Miroslav Medveď, PhD.
Tel: 58 563
4767, E-mail:
miroslav.medved@upol.cz, Room:
3.008
Research interests
- Non-linear optical properties of medium sized molecules and complexes (electron correlation, vibrational, and solvent effects)
- Electronic transitions (absorption, fluorescence, solvatochromism) and molecular properties in excited states
- Chemical modifications of graphene derivatives
Education
- 1989 - 1994 - M.Sc. Physical chemistry, Comenius University, Bratislava
- 1994 - 2002 - Ph.D. Chemical physics, Comenius University, Bratislava
- 2001 - RNDr. Environmental chemistry, Matej Bel University, Banská Bystrica
- 2008 - doc. (associate prof.) Theoretical and Computational Chemistry, Comenius University, Bratislava
Employment
- 1996 - 2005 - Researcher, Matej Bel University, Banská Bystrica
- 2005 - 2009 - Assistant professor, Matej Bel University, Banská Bystrica
- 2008 - 2016 - Head of the Department of Chemistry, Matej Bel University, Banská Bystrica
- 2009 - now - Associate professor, Matej Bel University, Banská Bystrica
- 2016 - now - Researcher (part-time), Palacký University, Olomouc (group of prof. Otyepka)
International experience
- 1999 - Stay at Max Planck Institute für Astrophysik, Garching, Germany; group of Prof. G. H. D. Diercksen
- 2002 - 2003 - OSTC-SSTC Research Fellowship in CTA, FUNDP, Namur, Belgium; group of Prof. J.-M. André
- 2005 - RTN stay at NHRC, Athens and ICEHT, Patras, Greece; groups of Prof. S. Couris and Dr. M. Papadopoulos
- 2013, 2015 - Stays at CEISAM, Université de Nantes, France; group of Prof. Denis Jacquemin
Cooperation
- Prof. Denis Jacquemin, Dr. Adèle Laurent, Université de Nantes, France
- Dr. Robert Zaleśny, Wrocław University of Science and Technology, Wroclaw, Poland
- Dr. Heribert Reis, National Hellenic Research Centre, Athens, Greece
- Groups of Prof. Miroslav Urban and Prof. Jozef Noga, Comenius University, Bratislava, Slovakia
- Dr. Drahomír Hnyk, Institute of Inorganic Chemistry, ASCR, Řež u Prahy
- and others
Grants, projects
- Leonardo da Vinci (EU) - Development of Educational Modules in Environmental Chemistry, 2000-2001
- APVT (SK) - Development and applications of the methodology for evaluating the nonlinear optical properties of organic molecules, 2004-2006
- VEGA (SK) - Study of nonlinear optical properties of conjugated oligomers containing carbon, nitrogen and boron, 2009-2011
- APVV-SK-PL - Long-range corrected DFT calculations of nonlinear optical properties of extended molecular systems, 2010-2011
- APVV (SK) - Interactions in bio and nanosystems, 2011-2014
- COST - COnvergent Distributed Environment for Computational Spectroscopy (CODECS), 2010-2014
- APVV-SK-FR - Solvent effects on excited state molecular properties: Bridging Experiment and Theory (BridgET), 2016-2017
- APVV (SK) - Noncovalent interactions in systems of increasing complexity, 2016-2019
- COST - MOLecules In Motion (MOLIM), 2015-2019
Supervized Ph.D. students
- Mária Stachová (2005 - 2009)
- Dagmar Matochová (2017 - )
Publication
2020
- Chronopoulos DD, Medved M, Potsi G, Tomanec O, Scheibe M, Otyepka M: Tunable one-step double functionalization of graphene based on fluorographene chemistry. Chem. Commun., 56, 1936-1939, 2020. (DOI)
- Siddique F, Langer M, Paloncýová M, Medved M, Otyepka M, Nachtigallová D, Lischka H, Aquino AJ: Conformational Behavior and Optical Properties of a Fluorophore Dimer as Model of Luminescent Centers in Carbon Dots. J. Phys. Chem. C, 124(26), 14327–14337, 2020. (DOI)
- Zaoralová D, Hrubý V, Šedajová V, Mach R, Kupka V, Ugolotti J, Bakandritsos A, Medved M, Otyepka M: Tunable Synthesis of Nitrogen Doped Graphene from Fluorographene under Mild Conditions. ACS Sustainable Chem. Eng., 8(12), 4764-4772, 2020. (DOI)
2019
- Bakandritsos A, Kadam RG, Kumar P, Zoppellaro G, Medved M, Tuček J, Montini T, Tomanec O, Andrýsková P, Drahoš B, Varma RS, Otyepka M, Gawande MB, Fornasiero P, Zbořil R: Mixed‐Valence Single‐Atom Catalyst Derived from Functionalized Graphene. Adv. Mater., 31(17), 1900323, 2019. (DOI)
- Bares H, Aristides B, Medved M, Ugolotti J, Jakubec P, Tomanec O, Kalytchuk S, Zbořil R, Otyepka M: Bimodal role of fluorine atoms in fluorographene chemistry opens a simple way toward double functionalization of graphene. Carbon, 145, 251-258, 2019. (DOI)
- Blanco M, Mosconi D, Otyepka M, Medved M, Aristides B, Agnoli S, Granozzi G: Combined high degree of carboxylation and electronic conduction in graphene acid set new limits for metal free catalysis in alcohol oxidation. Chem. Sci., 10, 9438-9445, 2019. (DOI)
- Chronopoulos DD, Medved M, Blonski P, Nováček Z, Jakubec P, Tomanec O, Bakandritsos A, Novotná V, Zbořil R, Otyepka M: Alkynylation of graphene via the Sonogashira C–C cross-coupling reaction on fluorographene. Chem. Commun., 55, 1088-1091 , 2019. (DOI)
- Hoorens MWH, Medved M, Laurent AD, Di Donato M, Fanetti S, Slappendel L, Hilbers M, Feringa BL, Buma WJ, Szymanski W: Iminothioindoxyl as a molecular photoswitch with 100 nm band separation in the visible range. Nat. Commun., 10, 2390, 2019. (DOI)
- Langer R, Zaoralová D, Medved M, Banáš P, Blonski P, Otyepka M: Variability of C–F Bonds Governs the Formation of Specific Structural Motifs in Fluorinated Graphenes. J. Phys. Chem. C, 123(45), 27896-27903, 2019. (DOI)
- Petr M, Jakubec P, Ranc V, Šedajová V, Langer R, Medved M, Blonski P, Kašlík J, Kupka V, Otyepka M, Zbořil R: Thermally reduced fluorographenes as efficient electrode materials for supercapacitors. Nanoscale, 11, 21364-21375, 2019. (DOI)
- Potsi G, Bourlinos AB, Mouselimis,Vasilios , Poláková K, Chalmpes N, Gournis D, Kalytchuk S, Tomanec O, Blonski P, Medved M, Lazar P, Otyepka M, Zbořil R: Intrinsic photoluminescence of amine-functionalized graphene derivatives for bioimaging applications. Appl. Mater. Today, 17, 112-122, 2019. (DOI)
2018
- Lerch MM, Di Donato M, Laurent AD, Medved M, Iagatti A, Bussotti L, Lapini A, Buma WJ, Foggi P, Szymański W, Feringa BL: Solvent Effects on the Actinic Step of Donor–Acceptor Stenhouse Adduct Photoswitching. Angew. Chem. Int. Ed., 130(27), 8195-8200, 2018. (DOI)
- Lerch MM, Medved M, Lapini A, Laurent AD, Iagatti A, Bussotti L, Szymanski W, Buma WJ, Foggi P, Di Donato M, Feringa BL: Tailoring Photoisomerization Pathways in Donor-Acceptor Stenhouse Adducts: The Role of the Hydroxyl Group. J. Phys. Chem. A, 122(4), 955–964, 2018. (DOI)
- Matochová D, Medved M, Aristides B, Steklý T, Zbořil R, Otyepka M: 2D Chemistry - Chemical Control of Graphene Derivatization. J. Phys. Chem. Lett., 9(13), 3580–3585, 2018. (DOI)
- Medved M, Zoppellaro G, Ugolotti J, Matochová D, Lazar P, Pospíšil T, Bakandritsos A, Tuček J, Zbořil R, Otyepka M: Reactivity of fluorographene is triggered by point defects: beyond the perfect 2D world. Nanoscale, 10, 4696-4707, 2018. (DOI)
- Tuček J, Holá K, Zoppellaro G, Blonski P, Langer R, Medved M, Susi T, Otyepka M, Zbořil R: Zigzag sp2 Carbon Chains Passing through an sp3 Framework: A Driving Force toward Room-Temperature Ferromagnetic Graphene ACS Nano, 12(12), 12847–12859, 2018. (DOI)
2017
- Di Donato M, Lerch MM, Lapini A, Laurent AD, Iagatti A, Bussotti L, Ihrig SP, Medved M, Jacquemin D, Szymański W, Buma WJ, Foggi P, Feringa BL: Shedding Light on the Photoisomerization Pathway of Donor–Acceptor Stenhouse Adducts. J. Am. Chem. Soc., 139(44), 15596–15599, 2017. (DOI)
- Medved M, Demissie T, McKee M, Hnyk D: The Behavior of a Paramagnetic System in Electric and Magnetic Fields as Exemplified by Revisiting Li@B10H14. Phys. Chem. Chem. Phys., 19, 12229-12236, 2017. (DOI)